How do I calculate the percent concentration of a solution?

Mass percent, mass/volume percent and volume percent of a solution, or how much solute to weigh for the % you want, with the steps and the usual slips.

g
g
For water, 1 mL weighs very close to 1 g (0.998 g at 20 °C).

Mass percent (w/w)

10%

Mass of the solution
250 g
Solute in 100 g of solution
10 g
In parts per million (ppm)
100,000

The most common slip: dividing by the solvent instead of the whole solution. 25 g in 225 g of water is 10%, not 11.1%.

  1. Solution = solute + solvent = 25 + 225 = 250 g
  2. % = solute ÷ solution × 100 = 25 ÷ 250 × 100 = 10%

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The percent concentration tells you how much of a substance is in every 100 parts of a solution. 25 g of salt dissolved in 225 g of water makes 250 g of solution, so the concentration is 25 ÷ 250 × 100 = 10% by mass. The calculator works out the three forms used in class, the lab and on labels, and the reverse: how much solute to weigh and how much water to add for the strength you want.

Three ways to write a percent

Form Formula Unit Typical use
Mass percent (w/w) solute (g) ÷ solution (g) × 100 g per 100 g chemistry exercises, alloys, concentrated acids
Mass/volume (w/v) solute (g) ÷ solution (mL) × 100 g per 100 mL medicine, biology labs
Volume percent (v/v) liquid (mL) ÷ solution (mL) × 100 mL per 100 mL alcohol, disinfectants

For dilute water solutions the three are close, because 1 mL of water weighs very nearly 1 g. For strong solutions they drift apart, and a label will say which one it means.

Worked examples

You have Calculation Concentration
10 g of sugar in 90 g of water 10 ÷ 100 × 100 10% w/w
10 g of sugar in 100 g of water 10 ÷ 110 × 100 9.09% w/w
50 g of salt in 200 g of water 50 ÷ 250 × 100 20% w/w
9 g of salt made up to 1,000 mL 9 ÷ 1,000 × 100 0.9% w/v
40 mL of ethanol made up to 100 mL 40 ÷ 100 × 100 40% v/v

The second line is the classic trap: adding 10 g to 100 g of water gives 9.09%, not 10%.

Making a solution

To make a given mass of solution at a given strength, weigh the solute first: solute = total × % ÷ 100, then the solvent is the rest. 1,000 g of a 0.9% solution needs 9 g of salt and 991 g of water. For w/v or v/v, dissolve or measure the solute, then top up with water to the final volume in a measuring cylinder or a volumetric flask, rather than adding the full volume of water.

To weaken a solution you already have, use the dilution calculator (C₁V₁ = C₂V₂). Both run on your device and work offline.

Frequently asked questions

How do I calculate mass percent?

Divide the mass of the solute by the mass of the whole solution (solute plus solvent) and multiply by 100. 25 g of salt in 225 g of water: 25 ÷ 250 × 100 = 10%.

What is the difference between w/w, w/v and v/v?

w/w is grams per 100 g of solution; w/v is grams per 100 mL of solution; v/v is milliliters per 100 mL of solution. Saline at 0.9% is w/v (0.9 g in every 100 mL); a 40% spirit is v/v.

How much salt do I need for 1 kg of a 5% solution?

5% of 1,000 g = 50 g of salt, dissolved in 950 g of water. Choose 'Make a solution' in the calculator.

Why is 25 g in 225 g of water not 11.1%?

Because the percentage is of the whole solution, 250 g, not of the water alone. Dividing by the solvent is a frequent slip in exercises.

How do I turn a percent into ppm?

Multiply by 10,000. A 0.05% solution is 500 parts per million (by mass when it is a mass percent).

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